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Gross–Pitaevskii equation : ウィキペディア英語版
Gross–Pitaevskii equation
The Gross–Pitaevskii equation (GPE, named after Eugene P. Gross and Lev Petrovich Pitaevskii) describes the ground state of a quantum system of identical bosons using the Hartree–Fock approximation and the pseudopotential interaction model.
In the Hartree–Fock approximation the total wave-function \Psi of the system of N bosons is taken as a product of single-particle functions \psi,
:
\Psi(\mathbf_1,\mathbf_2,\dots,\mathbf_N)=\psi(\mathbf_1)\psi(\mathbf_2)\dots\psi(\mathbf_N)

where \mathbf_i is the coordinate of the i-th boson.
The pseudopotential model Hamiltonian of the system is given as
:
H=\sum_^N \left(-+V(\mathbf_i)\right)
+\sum_\delta(\mathbf_i-\mathbf_j),

where m is the mass of the boson, V is the external potential, a_s is the boson-boson scattering length, and \delta(\mathbf) is the Dirac delta-function.
If the single-particle wave-function satisfies the Gross–Pitaevski equation,
:
\left(-\frac + V(\mathbf) + \vert\psi(\mathbf)\vert^2\right)\psi(\mathbf)=\mu\psi(\mathbf),

the total wave-function minimizes the expectation value of the model Hamiltonian under normalization condition \int dV |\Psi|^2=N.
It is a model equation for the single-particle wavefunction in a Bose–Einstein condensate. It is similar in form to the Ginzburg–Landau equation and is sometimes referred to as a nonlinear Schrödinger equation.
A Bose–Einstein condensate (BEC) is a gas of bosons that are in the same quantum state, and thus can be described by the same wavefunction. A free quantum particle is described by a single-particle Schrödinger equation. Interaction between particles in a real gas is taken into account by a pertinent many-body Schrödinger equation. If the average spacing between the particles in a gas is greater than the scattering length (that is, in the so-called dilute limit), then one can approximate the true interaction potential that features in this equation by a pseudopotential. The non-linearity of the Gross–Pitaevskii equation has its origin in the interaction between the particles. This is made evident by setting the coupling constant of interaction in the Gross–Pitaevskii equation to zero (see the following section): thereby, the single-particle Schrödinger equation describing a particle inside a trapping potential is recovered.
==Form of equation==

The equation has the form of the Schrödinger equation with the addition of an interaction term. The coupling constant, g, is proportional to the scattering length a_s of two interacting bosons:
:g=\frac,
where \hbar is the reduced Planck's constant and m is the mass of the boson.
The energy density is
:\mathcal=\frac\vert\nabla\Psi(\mathbf)\vert^2 + V(\mathbf)\vert\Psi(\mathbf)\vert^2 + \fracg\vert\Psi(\mathbf)\vert^4,
where \Psi is the wavefunction, or order parameter, and V is an external potential.
The time-independent Gross–Pitaevskii equation, for a conserved number of particles, is
:\mu\Psi(\mathbf) = \left(-\frac\nabla^2 + V(\mathbf) + g\vert\Psi(\mathbf)\vert^2\right)\Psi(\mathbf)
where \mu is the chemical potential. The chemical potential is found from the condition that the number of particles is related to the wavefunction by
:N = \int\vert\Psi(\mathbf)\vert^2 \, d^3r.
From the time-independent Gross–Pitaevskii equation, we can find the structure of a Bose–Einstein condensate in various external potentials (e.g. a harmonic trap).
The time-dependent Gross–Pitaevskii equation is
:i\hbar\frac = \left(-\frac\nabla^2 + V(\mathbf) + g\vert\Psi(\mathbf,t)\vert^2\right)\Psi(\mathbf,t).
From the time-dependent Gross–Pitaevskii equation we can look at the dynamics of the Bose–Einstein condensate. It is used to find the collective modes of a trapped gas.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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